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Reaction of cyclopropanamines with hypochlorite

✍ Scribed by Vaidyanathan, Ganesan; Wilson, Joseph W.


Book ID
120933703
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
866 KB
Volume
54
Category
Article
ISSN
0022-3263

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In a recent attempt to add t-butyl hypochlorite to olefins such as styrene and l-hexene in nitromethane, we were surprised to find that the exclusive products of these rapid reactions are chloronitromethane (ClCHaNO =,I) and t-butyl alcohol in nearly quantitative yield. This reaction is outlined in