Reaction of bullvalene with tetracyanoethylene and N-methyltriazolinedione
β Scribed by P. Cernuschi; C. De Michel; R. Gandolfi
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- French
- Weight
- 194 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
Bchrider et aliil have studied the reaction of bullvalene with tetracyanoethylene (TCNE): they isolated an adduct C ,OH,O. TCNE in benzene while in acetonitrile the products obtained were not characterized and considered polymeric substances. Product C ,oH,O.TCNE was po
π SIMILAR VOLUMES
Thermal reactions between electron-deficient ;r-systems and C-C I T bonds have previously been encountered only with highly strained cyclopropane compounds [I] such a s bicyclo-
The addition of N-methyltriazolinedione (M) to biadamantylidene (A) gives the [2 + 2) adduct P, but clearly does not proceed in one step beause an aminoaziridinium intermediate (I) can be observed to build up during the reaction. The overall rate of P formation correlates with the amount of I that b
## Abstract For Abstract see ChemInform Abstract in Full Text.