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Reaction of 1,1-Diphenylcyclopropane with Tetracyanoethylene

✍ Scribed by Dr. Th. Martini; Prof. Dr. J. A. Kampmeier

Publisher
John Wiley and Sons
Year
1970
Tongue
English
Weight
138 KB
Volume
9
Category
Article
ISSN
0044-8249

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✦ Synopsis

Thermal reactions between electron-deficient ;r-systems and C-C I T bonds have previously been encountered only with highly strained cyclopropane compounds [I] such a s bicyclo-

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## Abstract For Abstract see ChemInform Abstract in Full Text.

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Extraction with ethyl acetate or ether and distillation of the crude furnishes pure (2). As shown in the reaction scheme, the overall reaction proceeds via several unisolated intermediates and it has not yet been established whether the cyclization occurs with (la) or ( 1 b). Remarkably, in the pres