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Reaction of benzo[2.2]paracyclophane with singlet oxygen

โœ Scribed by Wasserman, H. H.; Keehn, P. M.

Book ID
125901150
Publisher
American Chemical Society
Year
1972
Tongue
English
Weight
328 KB
Volume
94
Category
Article
ISSN
0002-7863

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## Abstract The reaction of singlet oxygen with 2โ€phenylnorbornene (**1**) in aprotic solvents gives 3โ€formylcyclopentyl phenyl ketone (**2**) (10%) and uncharacterized polymer (90%). When methanol is used as solvent, __endo__โ€2โ€phenylโ€__exo__โ€2โ€methoxyโ€__exo__โ€3โ€hydroperoxynorbornane (**4**) and _