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Reaction of Bare VO+ and FeO+ with Ammonia: A Theoretical Point of View

✍ Scribed by Sandro Chiodo; Olga Kondakova; Maria del Carmen Michelini; Nino Russo; Emilia Sicilia

Publisher
John Wiley and Sons
Year
2004
Weight
58 KB
Volume
35
Category
Article
ISSN
0931-7597

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The dynamics of the reaction of Si Γ· with ammonia have been studied by means of an approximate classical trajectory method and RRKM theory, in combination with accurate computations of the minima and saddle points of the potential energy surface of the (SiNH3) + system, made using a slightly modifie

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## Abstract β€˜Bare’ FeO^+^ reacts in the gas phase with norbornane with collision efficiency, and the most prominent cationic products correspond to [FeC~5~H~6~]^+^ (32%), [FeC~7~H~8~]^+^ (19%), [FeC~3~H~6~O]^+^ (19%) and [FeC~6~H~6~]^+^ (14%), which are structurally characterized by ligand exchange