Reaction of azomethine ylides with sulfur ylides. Novel azetidine synthesis
β Scribed by Vaultier, Michel; Danion-Bougot, Renee; Danion, Daniel; Hamelin, Jack; Carrie, Robert
- Book ID
- 126394121
- Publisher
- American Chemical Society
- Year
- 1975
- Tongue
- English
- Weight
- 434 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0022-3263
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π SIMILAR VOLUMES
m : N-unsubstituted diazaarsoles 4 undergo an N alkylation by reaction with sulfur yliaks. N-substituted diazaarsoles 5. and 2 react with dimethylsulfoxonium ylide to give stable bicyclic arsiranei u and 12. Aziridines are well known precursors of azomethine ylides and we wondered if arsimnes could
A novel heterocyclic sulfur ylide, 2-t-butyl-3-methyl-1-phenylbenzothiazolinium ylide 13) was generated as an intermediate in the reaction of 2-t-butyl-3-methylbenzothiazolze (2) with benzyne. The S-ylide 13 underwent a novel intermolecular [1,2] shift to give 2-t-butyl-3-methyl-2-phenylbenzothiazom