The lithium derivatives (I) of 1,3-dithianes, which have established their value as nucleophilic acylating agents, react with a variety of alkyl halides and carbonyl compounds.
Reaction of Aziridinones with 2-Lithio-1, 3-Dithiane: Selective Cleavage of the Aziridinone Ring
โ Scribed by Talaty, Erach R.; Clague, Allen R.; Behrens, Jana M.; Agho, Michael O.; Burger, David H.; Hendrixson, Thomas L.; Korst, Katherine M.; Khanh, Tran T.; Kell, Roger A.; Dibaji, Nooshin
- Book ID
- 121245849
- Publisher
- Taylor and Francis Group
- Year
- 1981
- Tongue
- English
- Weight
- 238 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0039-7911
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the line-shape changes allow the detection of two different dynamic processes, which may be assigned to inhibited rotations about the partial C C and C N double bonds of the E-isomers (Scheme 2). Above ca. 0ยฐC conversion into the isomer with Z-configurated CC double bond, which contains an intramol
Two neck cleuvage reuctims, under carbanion \_~orming conditions, cJr the 1,3-dithiane ring system are reported.