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Mechanistic studies of 2-lithio-1,3-dithiane reactions with radical probes

โœ Scribed by Chung, Sung Kee; Dunn, Larson B.

Book ID
126116644
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
725 KB
Volume
49
Category
Article
ISSN
0022-3263

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๐Ÿ“œ SIMILAR VOLUMES

Reactions of 2-lithio-1,3-dithianes with
Reactions of 2-lithio-1,3-dithianes with aromatic substrates
โœ W.H. Baarschers; T.L. Loh ๐Ÿ“‚ Article ๐Ÿ“… 1971 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 97 KB

The lithium derivatives (I) of 1,3-dithianes, which have established their value as nucleophilic acylating agents, react with a variety of alkyl halides and carbonyl compounds.

Ring-Opening Reactions of 2-Lithio-1,3-d
Ring-Opening Reactions of 2-Lithio-1,3-dithiane and 2-Lithio-1,3,5-trithiane with Carbene Complexes of Chromium and Tungsten
โœ Prof. Dr. Helgard G. Raubenheimer; Prof. Dr. Ernst Otto Fischer; Priv.-Doz. Dr. ๐Ÿ“‚ Article ๐Ÿ“… 1981 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 219 KB ๐Ÿ‘ 1 views

the line-shape changes allow the detection of two different dynamic processes, which may be assigned to inhibited rotations about the partial C C and C N double bonds of the E-isomers (Scheme 2). Above ca. 0ยฐC conversion into the isomer with Z-configurated CC double bond, which contains an intramol