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Reaction of alicyclic reformatsky reagents with 2-arylmethylene-1,3-diphenylpropane-1,3-diones

โœ Scribed by N. F. Kirillov; E. A. Nikiforova; M. I. Vakhrin

Book ID
111461037
Publisher
Springer
Year
2011
Tongue
English
Weight
144 KB
Volume
81
Category
Article
ISSN
1070-3632

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The reaction of 2-benzylidene-1,3-diphenylpropanetrione (1a) with phosphorus ylides 2ac afforded the new phosphonium ylides 4a-c. Trialkyl phosphites 3a-c react with 1a to give the respective dialkyl phosphonate products 5a-c. On the other hand, the olefinic compounds 6 and 7 were isolated from the