The molecule of 2-benzyl-1,3-diphenylpropane-1,3-dione, C 22 H 18 O 2 , being a diketo tautomer, shows different stereochemistry from that of the closed-ring cis-ketoenol tautomer of the parent 1,3-diphenylpropane-1,3-dione. The molecular packing involves C-HÁ Á ÁO andstacking interactions.
Oxidation reactions of 1,3-diphenylpropane-1,3-dione
✍ Scribed by Medha Rele; B. S. Patro; S. Adhikari; G. P. Kalena; S. Chattopadhyay; T. Mukherjee
- Book ID
- 110644650
- Publisher
- Indian Academy of Sciences,Royal Society of Chemistry
- Year
- 2002
- Tongue
- English
- Weight
- 76 KB
- Volume
- 114
- Category
- Article
- ISSN
- 0253-4134
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📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 298 K Mean '(C±C) = 0.005 A Ê R factor = 0.031 wR factor = 0.085 Data-to-parameter ratio = 8.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
## 12 -085 1,3-Diphenylpropane-1,3-diamines. Part 11. Conversion of a 3-Hydroxy-1,3-diphenylpropan-1-one to 1,3-Diphenylpropane-1,3diamines. -Highly diastereoselective BH 3 •THF syn-reduction of the BBr 3 complex of hydroxypropanone (I) affords meso-diol (II), whereas a mixture of meso-diol (II) a