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Reaction of a sintered intermeta llic compound Ti2Ni with hydrogen

✍ Scribed by M. M. Antonova; S. N. Endrzheevskaya; A. G. Shablina; V. V. Skorokhod; O. T. Khorpyakov

Book ID: 104941523
Publisher: Springer
Year: 1984
Tongue: English
Weight: 433 KB
Volume: 23
Category: Article
ISSN: 1573-9066
DOI: 10.1007/bf00792148

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## Abstract **A happy ending**: The germanium(II) hydride [LGeH], where L=[HC{(CMe)(2,6‐__i__Pr~2~C~6~H~3~N)}~2~], reacts with a diazoalkane to form the hydrazone derivative (see picture). The reaction proceeds through the unprecedented end‐on nitrogen insertion of the diazo compound.magnified imag