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Reaction of a highly spiro-activated cyclopropane with pyridines. A novel intramolecular charge transfer interaction of the product

✍ Scribed by Ohkata, Katsuo; Tamaru, Akira; Nagai, Takashi; Hanafusa, Terukiyo

Book ID
121341625
Publisher
Royal Society of Chemistry
Year
1982
Tongue
English
Weight
509 KB
Volume
4
Category
Article
ISSN
1472-779X

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Reaction of non-activated olefins with C
Reaction of non-activated olefins with CH-acids; a novel method for the preparation of electrophilic cyclopropanes
✍ LΓ‘szlΓ³ TΓ³ke; GΓ‘bor T SzabΓ³; ZoltΓ‘n Hell; GΓ‘bor TΓ³th πŸ“‚ Article πŸ“… 1990 πŸ› Elsevier Science 🌐 French βš– 217 KB

Reaction of non-activated olefines with active methylene compounds was accomplished under solid-liquid phase-transfer conditions, in the presence of iodine, to give electrophilic cyclopropanes of a wide range of substituents. Several data to the mechanism of the reaction are also given.