Reaction of 5,6-dimethylene-7-oxabicyclo[2.2.1]hept-2-ene with iron carbonyls
✍ Scribed by Tristano Boschi; Pierre Vogel; Raymond Roulet
- Book ID
- 108351453
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- English
- Weight
- 202 KB
- Volume
- 133
- Category
- Article
- ISSN
- 0022-328X
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## Abstract Radical addition to 7‐oxabicylco[2.2.1]hept‐5‐en‐2‐one (1) was examined from a regiochemical point of view, and despite the small electronic anisotropy of the double bond, electrophilic radicals were found to add preferentially at C(5) with selectivities of up to 5:1. We also report the