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Reaction of 4-methyl-3,4-epoxytetrahydropyran with grignard reagents with isomerization to tetrahydrofuran derivatives

✍ Scribed by P. I. Kazaryan; N. M. Khizantsyan; A. A. Gevorkyan


Book ID
112348953
Publisher
Springer US
Year
1984
Tongue
English
Weight
63 KB
Volume
20
Category
Article
ISSN
0009-3122

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Treatment of homoallylic alcohols with NaIO 4 /NaHSO 3 reagent in aqueous t-BuOH under mild conditions produced tetrahydrofuran derivatives together with iodohydrins in a stereospecific manner. The reaction pathways of the formation of tetrahydrofurans from trans-and cis-homoallylic alcohols were fo