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Reaction of 3,6-di(tert-butyl)-1,2-benzoquinone with terminal alkylacetylenes in the presence of phosphorus trichloride

โœ Scribed by A. V. Nemtarev; V. F. Mironov; A. V. Bogdanov; V. K. Cherkasov; N. O. Druzhkov; A. T. Gubaidullin; I. A. Litvinov; R. Z. Musin


Publisher
Springer
Year
2009
Tongue
English
Weight
482 KB
Volume
58
Category
Article
ISSN
1573-9171

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The Reactions of 3,6-Di-tert-butyl-1,2-benzoquinone and 3,6-Ditert-butylcatechol with tert-Butyl Hydroperoxide. -The reaction of the title quinone (I) as well as its corresponding catechol with tert-butyl hydroperoxide in aprotic solvents results in ring oxidation accompanied by ring expansion furn