Reactions of lithium phenylacetylenide and lithium 3,3-dimethylbut-1-ynide with 3,6-di-tert-butyl-1,2-benzoquinone. Molecular structure of 2,5-di-tert-butyl-8-(3,6-di-tert-butyl-1,2-benzoquinon-4-yl)-8-phenylocta-2,4,6,7-tetraen-1,6-olide
β Scribed by G. A. Abakumov; N. N. Vavilina; V. I. Nevodchikov; V. K. Cherkasov; L. G. Abakumova; Yu. A. Kurskii; L. N. Zakharov
- Publisher
- Springer
- Year
- 1999
- Tongue
- English
- Weight
- 470 KB
- Volume
- 48
- Category
- Article
- ISSN
- 1573-9171
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π SIMILAR VOLUMES
The Reactions of 3,6-Di-tert-butyl-1,2-benzoquinone and 3,6-Ditert-butylcatechol with tert-Butyl Hydroperoxide. -The reaction of the title quinone (I) as well as its corresponding catechol with tert-butyl hydroperoxide in aprotic solvents results in ring oxidation accompanied by ring expansion furn
The title compound, C~21~H~30~Cl~2~N~4~O, contains a sterically hindered phenol group. The dihedral angle between the two rings is 72.3β (1)Β°. The propyl chain is disordered over two orientations.
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