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Reaction of 2,4,6-tri-tert-butylphenoxyl with oxygen in the presence of metal compounds

โœ Scribed by V. B. Vol'eva; E. V. Ivanov; I. A. Batanov; V. V. Ershov

Book ID
112444537
Publisher
Springer
Year
1986
Tongue
English
Weight
250 KB
Volume
35
Category
Article
ISSN
1573-9171

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Kinetics of the reactions of 2,4,6-tri-t
Kinetics of the reactions of 2,4,6-tri-t-butylphenoxyl with cumene hydroperoxide, cumylperoxyl radicals, and molecular oxygen
โœ A. P. Griva; E. T. Denisov ๐Ÿ“‚ Article ๐Ÿ“… 1973 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 318 KB

Reactions of 2,4,6-tri-t-butylphenoxyl (TBP) with cumene hydroperoxide (ROOH), cumylperoxyl radicals (RO,), and molecular oxygen in benzene solution have been investigated kinetically by the ESR method. The rate constant of the reaction TBP + ROOH -% TBPH + RO2 has been estimated in the temperature