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Kinetics and mechanism of reaction of 2,4,6-tri-tert-butylphenoxyl radicals with substituted dinitrosobenzenes

โœ Scribed by V. A. Khizhnyi; G. A. Goloverda

Book ID
112366456
Publisher
Springer
Year
1988
Tongue
English
Weight
495 KB
Volume
24
Category
Article
ISSN
0040-5760

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Kinetics of the reactions of 2,4,6-tri-t
Kinetics of the reactions of 2,4,6-tri-t-butylphenoxyl with cumene hydroperoxide, cumylperoxyl radicals, and molecular oxygen
โœ A. P. Griva; E. T. Denisov ๐Ÿ“‚ Article ๐Ÿ“… 1973 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 318 KB

Reactions of 2,4,6-tri-t-butylphenoxyl (TBP) with cumene hydroperoxide (ROOH), cumylperoxyl radicals (RO,), and molecular oxygen in benzene solution have been investigated kinetically by the ESR method. The rate constant of the reaction TBP + ROOH -% TBPH + RO2 has been estimated in the temperature