Reaction of 2,4-bis-O-(trimethylsilyl)-5-fluorouracil with selenium tetrabromide
✍ Scribed by R. Ya. Akhverdieva; é. Sh. Mamedov
- Publisher
- Springer US
- Year
- 1990
- Tongue
- English
- Weight
- 70 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0009-3122
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1 ,ZOxazines, bis(trimethylsily1)amino-substituted / Hydrogenolysis / Deprotonation / Alkylation / Deuteration 1,2-Oxazine 1 was converted into an unusual condensation product 5 by treatment with tetra-n-butylammonium fluoride. The hydrogenolysis of 1 with Pd/C as catalyst provided the expected prim
The photochemical reaction of 2,6-bis(trimethylsilyl)-4H-pyran with various a-ketoesters gave moderate to good yields of new bis(silylated) 4H-pyrans functionalized in position 4. In some cases, an oxidation byproduct was also isolated.