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Reaction of perchloro-3, 5-diazahepta-2, 4-diene with trimethylsilyl cyanide

✍ Scribed by Yu.I Matveyev; S.V Sereda; V.I Gorbatenko


Publisher
Elsevier Science
Year
1992
Tongue
French
Weight
170 KB
Volume
33
Category
Article
ISSN
0040-4039

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Reductive disilylation (Li + Me 3 SiCl Γ€ THF) of 1,3-cyclohexadiene led to 4,4 0 -bis(trimethylsilyl)bicyclohexyl-2,2 0 -diene (1). In the presence of TiCl 4 in dichloromethane, 1 reacted with some acyl chlorides, anhydrides, and aldehydes to give tricyclo[7.4.0.0 3,8 ]trideca-4,12-diene-2-yl deriva