Reaction rate constartls of SiHI(%'At) have been directly measured for the first time using the laser photolysis-laser-induced fluorescence method. The preparation of SiH: radical in the laser photolysis (193 m-n) or phenylsilane and the concentration of the radiczd is demonstrated by a dye laser at
✦ LIBER ✦
Reaction of [2-(SiH 3 )C 6 H 4 ] 2 SiH 2 with Ni(Et 2 PCH 2 CH 2 PEt 2 )(PEt 3 ) 2 : Characterization of η 2 -(Si−H)Ni and Ni IV −H Complexes
✍ Scribed by Chen, Wanzhi; Shimada, Shigeru; Tanaka, Masato; Kobayashi, Yuka; Saigo, Kazuhiko
- Book ID
- 126082539
- Publisher
- American Chemical Society
- Year
- 2004
- Tongue
- English
- Weight
- 73 KB
- Volume
- 126
- Category
- Article
- ISSN
- 0002-7863
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Frau Professor Marianne Baudler zum 80. Geburtstag gewidmet Inhaltsu È bersicht. t Bu 2 P±P=P(Me) t Bu 2 (1) bildet mit (Et 3 P) 2 NiCl 2 (2) und Na(Nph) das [l-(1,3 : 2,3-gt Bu 2 P 4 t Bu 2 ){Ni(PEt 3 )Cl} 2 ] (3) als Hauptprodukt. Mit Na/Hg als Reduktionsmittel entstehen dagegen die Ni 0 -Verbindu
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