Reaction of 2-cyanomethylbenzimidazole with alkyl halides
β Scribed by V. A. Anisimova; O. I. Askalepova; K. N. Bagdasarov; M. S. Chernov'yants
- Publisher
- Springer US
- Year
- 1988
- Tongue
- English
- Weight
- 389 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0009-3122
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π SIMILAR VOLUMES
A synthesis is described of alkyl chlorides by reaction of methoxy hydroperoxides, prepared from 1-alkenes by oronisation in methanol, with ferric chloride: RCH-CH,\_\*RCH(OOH)OCH,\_\*R= -?RCl. Yields of 1-chlorotetradecane were about 60%; those of other halides from 38 to 57%. INTRGDUCTION When alk
Nickel-and palladium-catalyzed cross-coupling reactions of organic halides with organometallic reagents is one of the most versatile carbonΒ±carbon bond-forming reactions in organic synthesis. [1] In most cases, aryl and vinyl halides are employed as organic halides, yielding sp 2 Β±sp, sp 2 Β±sp 2 , a