## Abstract Treatment of a mixture of epoxide and styrene with trimethylsilylmethylmagnesium bromide in the presence of a cobalt‐phosphine complex afforded homocinnamyl alcohol in good yield. The reaction should begin with ring opening of the epoxide by the action of magnesium bromide which leads t
Cobalt-Catalyzed Heck-Type Reaction of Alkyl Halides with Styrenes.
✍ Scribed by Yousuke Ikeda; Tomoaki Nakamura; Hideki Yorimitsu; Koichiro Oshima
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 35 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0931-7597
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📜 SIMILAR VOLUMES
Nickel-and palladium-catalyzed cross-coupling reactions of organic halides with organometallic reagents is one of the most versatile carbon±carbon bond-forming reactions in organic synthesis. [1] In most cases, aryl and vinyl halides are employed as organic halides, yielding sp 2 ±sp, sp 2 ±sp 2 , a
Nickel-and palladium-catalyzed cross-coupling reactions of organic halides with organometallic reagents is one of the most versatile carbon±carbon bond-forming reactions in organic synthesis. [1] In most cases, aryl and vinyl halides are employed as organic halides, yielding sp 2 ±sp, sp 2 ±sp 2 , a
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