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Reaction of 2-acylamino-3,3-dichloroacrylonitriles with methyl sulfanylacetate

✍ Scribed by S. V. Popil’nichenko; S. G. Pil’o; V. S. Brovarets; B. S. Drach

Book ID: 106522530
Publisher: Springer
Year: 2004
Tongue: English
Weight: 36 KB
Volume: 74
Category: Article
ISSN: 1070-3632
DOI: 10.1007/s11176-005-0075-7

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## Abstract Available 2‐acylamino‐3,3‐dichloroacrylonitriles, when treated with hydrazine hydrate, provide 2‐alkyl‐ or 2‐aryl‐5‐hydrazino‐1,3‐oxazole‐4‐carbonitriles that readily add alkyl or aryl isothiocyanates and the adducts formed recyclize on heating. Finally, the synthesis results in 5‐alkyl