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Reaction of 1,1,3,3-Tetraoxa-2,2-dibromo- 4,4,5,5,6,6-hexafluoro-1,3-dithiacyclohexane with Pyrazine and Hexamethylphosphoramide: Unexpected Cocrystals through Halogen Bonding

✍ Scribed by Zhu, Shizheng; Jiang, Huiling; Zhao, Jingwei; Li, Zhanting

Book ID
120535185
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
249 KB
Volume
5
Category
Article
ISSN
1528-7483

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✍ Binoy K. Saha; Ashwini Nangia 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 281 KB

## Abstract Crystal structures of 2,4,6‐tris(2‐halophenoxy)‐1,3,5‐triazines (halo = fluoro, chloro, bromo, iodo; 2‐XPOT) are discussed in the background of 3‐halophenoxy (3‐XPOT) and 4‐halophenoxy (4‐XPOT) structures. Among inter‐halogen interactions, the electrostatic L‐shaped type II interactions