Reaction of 1-Zirconacyclopent-3-yne with “Zirconocene”: Synthesis and Structure of Bimetallic 1,2,3-Butatriene Complexes 1
✍ Scribed by Suzuki, Noriyuki; Watanabe, Takaaki; Iwasaki, Masakazu; Chihara, Teiji
- Book ID
- 126205368
- Publisher
- American Chemical Society
- Year
- 2005
- Tongue
- English
- Weight
- 117 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0276-7333
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Preparation of 8 a: Complex 3 (75.3 mg, 0.105 mmol) and KC 8 (46 mg; K atoms: 0.25 mmol) were suspended in THF (1.5 mL) at room temperature, and the resulting mixture was stirred for 1 h. The deep blue mixture was then cooled to À78 8C, and iodomethane (68 mg, 0.48 mmol) was added dropwise. The mixt
Preparation of 8 a: Complex 3 (75.3 mg, 0.105 mmol) and KC 8 (46 mg; K atoms: 0.25 mmol) were suspended in THF (1.5 mL) at room temperature, and the resulting mixture was stirred for 1 h. The deep blue mixture was then cooled to À78 8C, and iodomethane (68 mg, 0.48 mmol) was added dropwise. The mixt