Reaction mechanism for the complete heterogeneous catalytic oxidation of chlorine derivatives of benzene
β Scribed by Yu. V. Belokopytov; I. V. Davidenko
- Book ID
- 112366654
- Publisher
- Springer
- Year
- 1993
- Tongue
- English
- Weight
- 226 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0040-5760
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The chlorine evolution reaction was investigated on several oxide electrodes. The active site on the electrode surface is concluded to be the metal site, based on the dependence of the anodic current on pH of the electrolyte. The reaction mechanism can be determined by the d-electron configuration i
## Abstract The title reaction, displaying peculiar characteristics as to relative rates and isomer distributions, has been studied in detail. Prior to this study, different mechanisms had been advanced by several groups. Kinetic features (isomer patterns, relative and absolute rates, reaction orde