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Reaction kinetics of resveratrol with tert-butoxyl radicals

✍ Scribed by Iva Džeba; Tomasz Pedzinski; Branka Mihaljević


Book ID
116855787
Publisher
Elsevier Science
Year
2012
Tongue
English
Weight
213 KB
Volume
81
Category
Article
ISSN
0969-806X

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## Abstract It has been shown by ESR spectroscopy that the title reaction involves abstraction of hydrogen from the phosphite, since at −10°C the reaction has a kinetic deuterium isotope effect, k~H~/k~D~, or ∼3. The rate constant for hydrogen abstraction is __c__. 2 × 10^4^ M^−1^ s^−1^. There is n

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