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Reaction Kinetics for the Anionic Ring-Opening Polymerization of Tetraphenyltetramethylcyclotetrasiloxane Using a Fast Initiator System

✍ Scribed by Mark E. Van Dyke; Stephen J. Clarson


Book ID
110420680
Publisher
Springer
Year
1998
Tongue
English
Weight
303 KB
Volume
8
Category
Article
ISSN
1053-0495

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## Abstract Methanol, in combination with a non‐ionic phosphazene base, was used to initiate the polymerization of octamethylcyclotetrasiloxane. In bulk, an instantaneous and large increase in viscosity was observed upon addition of the initiator. In toluene solution, the equilibrium state was reac