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Reaction entropy for the electroreduction of 2-phenyl-3-arylimino-3H-indoles in various aprotic solvents

✍ Scribed by G. Marrosu; F. Rodante; A. Trazza; L. Greci


Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
650 KB
Volume
168
Category
Article
ISSN
0040-6031

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Nucleophilic second-order rate constants, k n ms , for the reactions of several primary and secondary amines with ionized phenyl salicylate (PS Οͺ ) show a nonlinear decrease with the increase in the content of CH 3 CN from 2 to Υ…50% v/v in mixed aqueous solvent. The values of k n ms remain almost un