๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Reaction enthalpies and activation energies of two important reactions in flame suppression by CF3Br

โœ Scribed by E.P.F Lee; J.M Dyke; F.-T Chau; W.-K Chow; D.K.W Mok

Book ID
104108298
Publisher
Elsevier Science
Year
2003
Tongue
English
Weight
191 KB
Volume
376
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

โœฆ Synopsis

Reaction enthalpies and activation energies of the reactions: CF 3 Br ! CF 3 + Br and CF 3 Br + H ! CF 3 + HBr, were calculated at near state-of-the-art level, and compared with available experimental values and values employed in kinetic modelling of flame suppression. An ab initio strategy for evaluating reliable reaction enthalpies and activation energies for reactions considered in kinetic modelling of fire inhibition is recommended.

๐Ÿ“œ SIMILAR VOLUMES

The kinetics and equilibrium of the gas-
The kinetics and equilibrium of the gas-phase reaction CH3CF2Br + I2 = CH3CF2I + IBr the C-Br bond dissociation energy in 1,1-difluorobromoethane
โœ J. M. Pickard; A. S. Rodgers ๐Ÿ“‚ Article ๐Ÿ“… 1977 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 388 KB

The kinetics and equilibrium of the gas-phase reaction of CHaCFZBr with IZ were studied spectrophotometrically from 581 to 662ยฐK and determined to be consistent with the following mechanism: KIZ