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Reaction chemistry of tris(trimethylsilyl)amine with monohaloboranes

โœ Scribed by Janik, Jerzy F.; Narula, Chaitanya K.; Gulliver, Eric G.; Duesler, E. N.; Paine, Robert T.


Book ID
126827929
Publisher
American Chemical Society
Year
1988
Tongue
English
Weight
784 KB
Volume
27
Category
Article
ISSN
0020-1669

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The reaction of tris(trimethylsilyl)sila
โœ M. Ballestri; C. Chatgilialoglu; N. Cardi; A. Sommazzi ๐Ÿ“‚ Article ๐Ÿ“… 1992 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 268 KB

Tris(trimethylsilyl)silane, in contrast with tributyltin hydride, reduces acid chlorides to the corresponding decarboxylated hydrocarbons via a free radical mechanism. This methodology could be a viable alternative to Barton's decarboxylation reaction. Tributyltin hydride reacts spontaneously at amb