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The reaction of tris(trimethylsilyl) silyllithium with aliphatic ketones

✍ Scribed by Ronald Wustrack; Hartmut Oehme

Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
788 KB
Volume
352
Category
Article
ISSN
0022-328X

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Tris(trimethylsilyl)silane, in contrast with tributyltin hydride, reduces acid chlorides to the corresponding decarboxylated hydrocarbons via a free radical mechanism. This methodology could be a viable alternative to Barton's decarboxylation reaction. Tributyltin hydride reacts spontaneously at amb