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Reaction between S -Nitrosothiols and Thiols: Generation of Nitroxyl (HNO) and Subsequent Chemistry

✍ Scribed by Wong, Patrick S.-Y.; Hyun, Jinjoo; Fukuto, Jon M.; Shirota, Frances N.; DeMaster, Eugene G.; Shoeman, Don W.; Nagasawa, Herbert T.

Book ID
126116233
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
376 KB
Volume
37
Category
Article
ISSN
0006-2960

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## Abstract Thermal or photolytic reactions of bioactive __S__‐nitrosothiols and related thiols in the presence of radical generators in deaerated DMSO or aqueous solutions under argon or saturated with nitric oxide (NO) produced nitroxides and an oxyaminyl radical, which were well characterized by