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Rb4YbI6Synthesis and Crystal Structure

✍ Scribed by Wang Meitian; Wang Shihua


Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
262 KB
Volume
128
Category
Article
ISSN
0022-4596

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✦ Synopsis


The divalent rare earth compound-Rb 4 YbI 6 was prepared by a one-step method. Using X-ray powder diffraction data, its crystal structure has been determined and refined by the Rietveld technique to R WP ‫1.11؍‬ by isotype with compound Cs 4 PbBr 6 . The crystal symmetry is trigonal, a‫)1(051.41؍‬ A s , c‫)3(364.71؍‬ A s , space group R3 c (167), Z‫.6؍‬ The Yb and I atoms form isolated, slightly distorted [YbI 6 ] 4؊ octahedra, which are linked via Rb Ψ‰ to form chains along the c-axis. The other three Rb Ψ‰ hold these chains together to form the crystal structure. 1997 Academic Press


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