The new compound Rb 2 CdSiO 4 has been synthesized from Rb 2 CdO 2 and SiO 2 in the presence of excess Rb 2 O (typical molar ratio 1:1:2) under Ar atmosphere in a sealed Ag container at 3303 3C (40d). The twinned structure has been re5ned from X-ray single crystal data. Rb 2 CdSiO 4 was found to cry
Rb4YbI6Synthesis and Crystal Structure
β Scribed by Wang Meitian; Wang Shihua
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- English
- Weight
- 262 KB
- Volume
- 128
- Category
- Article
- ISSN
- 0022-4596
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β¦ Synopsis
The divalent rare earth compound-Rb 4 YbI 6 was prepared by a one-step method. Using X-ray powder diffraction data, its crystal structure has been determined and refined by the Rietveld technique to R WP β«1.11Ψβ¬ by isotype with compound Cs 4 PbBr 6 . The crystal symmetry is trigonal, aβ«)1(051.41Ψβ¬ A s , cβ«)3(364.71Ψβ¬ A s , space group R3 c (167), Zβ«.6Ψβ¬ The Yb and I atoms form isolated, slightly distorted [YbI 6 ] 4Ψ octahedra, which are linked via Rb Ψ to form chains along the c-axis. The other three Rb Ψ hold these chains together to form the crystal structure. 1997 Academic Press
π SIMILAR VOLUMES
The synthesis of a hitherto unknown 6 : 5 phase in the quasi-binary system RbCl/PbCl 2 and its structure determination is reported. The compound Rb 6 Pb 5 Cl 16 crystallizes in the tetragonal space group P4/mbm with a large variety of different coordination polyhedra for the cations. Special feature
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
Synthesis and Crystal Structure of Rb 6 Pb 5 Cl 16 . -The hitherto unknown 6:5 phase of title is prepared by reaction of appropriate amounts of RbCl and PbCl 2 (sealed silica tube, 1. 500 β’ C, 0.5 h, 2. 335 β’ C, several weeks). Rb 6 Pb 5 Cl 16 crystallizes in the tetragonal space group P4/mbm (pow