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Rb3P6N11 and Cs3P6N11—New Highly Condensed Nitridophosphates by High-Pressure High-Temperature Synthesis

✍ Scribed by Kai Landskron; Wolfgang Schnick

Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
183 KB
Volume
156
Category
Article
ISSN
0022-4596

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A new stannosilicate Cs 2 SnSi 3 O 9 has been synthesized and characterized by single-crystal X-ray diffraction and solid-state NMR spectroscopy. It crystallizes in the orthorhombic space group P2 1 2 1 2 1 (No. 19) with a ¼ 7:9612ð7Þ ( A; b ¼ 10:3444ð9Þ ( A; c ¼ 11:780ð1Þ ( A; V ¼ 970:1ð3Þ ( A 3 ;