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Rationally tuned micropores within enantiopure metal-organic frameworks for highly selective separation of acetylene and ethylene

✍ Scribed by Xiang, Sheng-Chang; Zhang, Zhangjing; Zhao, Cong-Gui; Hong, Kunlun; Zhao, Xuebo; Ding, De-Rong; Xie, Ming-Hua; Wu, Chuan-De; Das, Madhab C.; Gill, Rachel; Thomas, K. Mark; Chen, Banglin


Book ID
120416091
Publisher
Nature Publishing Group
Year
2011
Tongue
English
Weight
806 KB
Volume
2
Category
Article
ISSN
2041-1723

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A Microporous Metal–Organic Framework fo
✍ Dr. Yabing He; Dr. Zhangjing Zhang; Dr. Shengchang Xiang; Dr. Frank R. Fronczek; 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 598 KB

## Abstract A novel three‐dimensional microporous metal–organic framework Zn~4~L(DMA)~4~ (**UTSA‐33**, H~8~L=1,2,4,5‐tetra(5‐isophthalic acid)benzene, DMA=__N__,__N__′‐dimethylacetamide) with small pores of about 4.8 to 6.5 Å was synthesized and structurally characterized as a non‐interpenetrated (