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A new microporous metal–organic framework with potential for highly selective separation methane from acetylene, ethylene and ethane at room temperature

✍ Scribed by Duan, Xing; Zhang, Qi; Cai, Jianfeng; Cui, Yuanjing; Wu, Chuande; Yang, Yu; Qian, Guodong

Book ID
123534037
Publisher
Elsevier Science
Year
2014
Tongue
English
Weight
810 KB
Volume
190
Category
Article
ISSN
1387-1811

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## Abstract A novel three‐dimensional microporous metal–organic framework Zn~4~L(DMA)~4~ (**UTSA‐33**, H~8~L=1,2,4,5‐tetra(5‐isophthalic acid)benzene, DMA=__N__,__N__′‐dimethylacetamide) with small pores of about 4.8 to 6.5 Å was synthesized and structurally characterized as a non‐interpenetrated (