Trimethylsilyl substitutions of the fenchyl alcohols [(1R,2R,4S)-exo-(2-Ar)-1,3,3-trimethylbicyclo[2.2.1]heptan-2ol, Ar = 2-methoxyphenyl (1) and Ar = 2-(dimethylaminomethyl)phenyl (2)] yield the chiral ligands 3 [Ar = 2-methoxy-3-(trimethylsilyl)phenyl] and 4 [Ar = 2-(dimethylaminomethyl)-3-(trimet
✦ LIBER ✦
Rationalization of Enantioselectivities in Dialkylzinc Additions to Benzaldehyde Catalyzed by Fenchone Derivatives †
✍ Scribed by Goldfuss, Bernd; Steigelmann, Melanie; Khan, Saeed I.; Houk, K. N.
- Book ID
- 127385471
- Publisher
- American Chemical Society
- Year
- 2000
- Tongue
- English
- Weight
- 167 KB
- Volume
- 65
- Category
- Article
- ISSN
- 0022-3263
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