Rational Design of Homochiral Solids Based on Two-Dimensional Metal Carboxylates
β Scribed by Yong Cui; Owen R. Evans; Helen L. Ngo; Peter S. White; Wenbin Lin
- Publisher
- John Wiley and Sons
- Year
- 2002
- Tongue
- English
- Weight
- 146 KB
- Volume
- 114
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
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## Abstract The hydrothermal reactions of Zn(ClO~4~)~2~Β·6H~2~O/Cu(NO~3~)~2~Β·6H~2~O with 5β(4βpyridyl)tetrazole in an ethanol/water or ethanol/water/pyridine medium yield one 2D and one 3D metalβorganic coordination framework [Zn~2~(OH)(4βptz)~3~] (1) and [Cu(4βptz)Β·0.5(py)] (3) [4βptz = 5β(4βpyridy
## Abstract Reaction of a pyridinecarboxylate ligand with copper salt affords a novel coordinative polymer [Cu(bpdc)(H~2~O)~2~Β·2H~2~O]n (bpdc=.2,2'βbipyridylβ3,3'βdicarboxylate). It has 2βD (4,4) layered network extended by the tetradentate bridging ligands, further interestingly, the coordinative