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Rational design of chiral stationary phases for capillary supercritical fluid chromatography.

✍ Scribed by Bryant E. Rossiter; Patrik Petersson; Deborah F. Johnson; Masakatsu Eguchi; Jerald S. Bradshaw; Karin E. Markides; Milton L. Lee


Book ID
104216187
Publisher
Elsevier Science
Year
1991
Tongue
French
Weight
249 KB
Volume
32
Category
Article
ISSN
0040-4039

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✦ Synopsis


A new class of chiral copolymers consisting of chiral organic and dimethylsiloxane units is described. One example of such copolymers, containing alternating diamide and dimethylsiloxane units, has been synthesized.

Using these chiral materials as stationary phases in capillary columns, chiral diols can be efficiently resolved by supercritical fluid chromatography.


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