The kinetics of the decay of hydroxyl radicals in the presence of excess acetylene were studied at pressures in the vicinity of 1 torr and at ambient temperature in a tubular discharge-flow reactor. Hydroxyl radicals were produced by the reaction of atomic hydrogen with nitrogen dioxide, H + NOZ + O
โฆ LIBER โฆ
Rates of reaction of the hydroxyl radical
โ Scribed by Thomas, J. K.
- Book ID
- 118005862
- Publisher
- Royal Society of Chemistry
- Year
- 1965
- Weight
- 390 KB
- Volume
- 61
- Category
- Article
- ISSN
- 0014-7672
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The relative rate technique has been used to measure the rate coefficient for the reaction of the hydroxyl radical (OH) with methyl isobutyrate (MIB, (CH 3 ) 2 CHC(ฯญO)-O-CH 3 ) to be (1.7 ฯฎ 0.4) ฯซ 10 ฯช12 cm 3 molecule ฯช1 s ฯช1 at 297 ฯฎ 3 K and 1 atmosphere total pressure. To more clearly define MIB's