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Rates of decompositions of certain AZO compounds

✍ Scribed by J. C. McGowan; T. Powell

Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
335 KB
Volume
81
Category
Article
ISSN
0165-0513

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✦ Synopsis

Abstract

The rates of decompositions of a number of azo compounds have been measured and some relationships between these rates and the structures of the azo compounds have been noted.

πŸ“œ SIMILAR VOLUMES

Free-Radical Decomposition of Azo Compou
Free-Radical Decomposition of Azo Compounds Induced by Organotin Hydrides
✍ Prof. Dr. W. P. Neumann; Dipl.-Chem. H. Lind πŸ“‚ Article πŸ“… 1967 πŸ› John Wiley and Sons 🌐 English βš– 204 KB

chemical shift difference (A8 = 2.4-2.9 ppm) between the axial (Ha) and equatorial (He) protons of the cis-methylene group. In contrast, the corresponding chemical shift difference of the trans-methylene groxp is much smaller (A% = 1-1.4 PPm). R 4-Bromoheptane 2-Bromoheptane 2-Bromooctane

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Investigation of the decomposition of compounds containing azo groups by EPR spectroscopy
✍ A. StaΕ‘ko; K. ErentovΓ‘; P. Rapta; O. Nuyken; B. Voit πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 809 KB

In photochemically, electrochemically and thermally initiated decomposition, compounds containing the azo group (1RNxN2R) usually form reactive, short-lived radicals and which corresponds to synchro-1R~2R~, nous splitting. As examples, aliphatic azo compounds, 1-aryl-2-alkylazo compounds, azophospho