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The photochemical decomposition of azo compounds (a spin trap study)

✍ Scribed by Andrej Staško; Katarina Szaboova; Vladimír Cholvad; Oskar Nuyken; Jochen Dauth


Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
710 KB
Volume
69
Category
Article
ISSN
1010-6030

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ESR parameters of 5,5-dimethylpyrrolidin
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## Abstract Splitting constants and __g__ values are reported for 5,5‐dimethylpyrrolidine 1‐oxide spin adducts with radicals such as substituted‐Ph˙, NaSO~3~˙, PhS~2~˙, and others observed in the photochemical decomposition of azo compounds in various solvents.

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In photochemically, electrochemically and thermally initiated decomposition, compounds containing the azo group (1RNxN2R) usually form reactive, short-lived radicals and which corresponds to synchro-1R~2R~, nous splitting. As examples, aliphatic azo compounds, 1-aryl-2-alkylazo compounds, azophospho