The photochemical decomposition of azo compounds (a spin trap study)
✍ Scribed by Andrej Staško; Katarina Szaboova; Vladimír Cholvad; Oskar Nuyken; Jochen Dauth
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 710 KB
- Volume
- 69
- Category
- Article
- ISSN
- 1010-6030
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## Abstract Splitting constants and __g__ values are reported for 5,5‐dimethylpyrrolidine 1‐oxide spin adducts with radicals such as substituted‐Ph˙, NaSO~3~˙, PhS~2~˙, and others observed in the photochemical decomposition of azo compounds in various solvents.
In photochemically, electrochemically and thermally initiated decomposition, compounds containing the azo group (1RNxN2R) usually form reactive, short-lived radicals and which corresponds to synchro-1R~2R~, nous splitting. As examples, aliphatic azo compounds, 1-aryl-2-alkylazo compounds, azophospho