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Rate of Thermal Isomerization of cis-Butene-2

✍ Scribed by Anderson, W. French; Bell, Jerry A.; Diamond, Jared M.; Wilson, Kent R.

Book ID
127296277
Publisher
American Chemical Society
Year
1958
Tongue
English
Weight
320 KB
Volume
80
Category
Article
ISSN
0002-7863

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πŸ“œ SIMILAR VOLUMES

H2S-promoted thermal isomerization of bu
H2S-promoted thermal isomerization of butene-2 CIS to butene-1 or butene-2 trans around 500Β°C
✍ C. Richard; A. Boiveaut; R. Martin πŸ“‚ Article πŸ“… 1980 πŸ› John Wiley and Sons 🌐 English βš– 470 KB

H2S increases the thermal isomerization of butene-2 cis (B,) to butene-1 (B1) and butene-2 trans (Bt) around 500Β°C. This effect is interpreted on the basis of a free radical mechanism in which buten-2-yl and thiyl free radicals are the main chain carriers. B1 formation is essentially explained by th

Thermal isomerization of cis- or trans-2
Thermal isomerization of cis- or trans-2-butene. The unimolecular elimination of hydrogen from cis-2-butene around 500Β°C
✍ D. Masson; C. Richard; R. Martin πŸ“‚ Article πŸ“… 1976 πŸ› John Wiley and Sons 🌐 English βš– 300 KB

## Abstract An analytical and kinetic study of the thermal reaction of __cis__‐ or __trans__‐2‐butene has been performed in a static system over the temperature range of 480–550Β°C and at a low extent of reaction and initial pressures of 10–100 torr. The rate constant of the unimolecular __cis–tran