𝔖 Bobbio Scriptorium
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Isomerization or “intramolecular metathesis” of cis-2-butene

✍ Scribed by J. Engelhardt


Book ID
113176544
Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
217 KB
Volume
72
Category
Article
ISSN
0021-9517

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H2S-promoted thermal isomerization of bu
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H2S increases the thermal isomerization of butene-2 cis (B,) to butene-1 (B1) and butene-2 trans (Bt) around 500°C. This effect is interpreted on the basis of a free radical mechanism in which buten-2-yl and thiyl free radicals are the main chain carriers. B1 formation is essentially explained by th

Thermal isomerization of cis- or trans-2
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## Abstract An analytical and kinetic study of the thermal reaction of __cis__‐ or __trans__‐2‐butene has been performed in a static system over the temperature range of 480–550°C and at a low extent of reaction and initial pressures of 10–100 torr. The rate constant of the unimolecular __cis–tran