H2S increases the thermal isomerization of butene-2 cis (B,) to butene-1 (B1) and butene-2 trans (Bt) around 500°C. This effect is interpreted on the basis of a free radical mechanism in which buten-2-yl and thiyl free radicals are the main chain carriers. B1 formation is essentially explained by th
✦ LIBER ✦
Isomerization or “intramolecular metathesis” of cis-2-butene
✍ Scribed by J. Engelhardt
- Book ID
- 113176544
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- English
- Weight
- 217 KB
- Volume
- 72
- Category
- Article
- ISSN
- 0021-9517
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