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Rate of Oxidation of Aromatic Hydrocarbons by Lead Tetraacetate 1

✍ Scribed by Fieser, Louis F.; Putnam, Stearns T.

Book ID
125502196
Publisher
American Chemical Society
Year
1947
Tongue
English
Weight
674 KB
Volume
69
Category
Article
ISSN
0002-7863

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The effect of a-silyl substitution on the oxidation of alcohols by lead tetraacetate has been evaluated. Under typical conditions for converting alcohols to cyclic ethers, ct-hydroxysilanes are instead efficiently transformed into mixed acetyl-silyl acetals.