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Rate of Interfacial Electron Transfer through the 1,2,3-Triazole Linkage

โœ Scribed by Devaraj, Neal K.; Decreau, Richard A.; Ebina, Wataru; Collman, James P.; Chidsey, Christopher E. D.


Book ID
118235266
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
173 KB
Volume
110
Category
Article
ISSN
0022-3654

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## Abstract Electroabsorption (Stark effect) measurements on the intervalence chargeโ€transfer (IVCT) transitions in the diastereoisomers of [{Ru(bpy)~2~}~2~(ฮผโ€bpt^โ€“^)]^4+^ [bpy = 2,2โ€ฒโ€bipyridine, bpt^โ€“^ = 3,5โ€bis(2โ€pyridyl)โ€1,2,4โ€triazolate] in __n__โ€butyronitrile glass at 77 K reveal effective cha