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Rate of initiation in photodegradation of poly(methyl methacrylate)

โœ Scribed by V.V. Selikhov; V.B. Ivanov; V.Ya. Shlyapintokh


Book ID
116047888
Publisher
Elsevier Science
Year
1986
Weight
284 KB
Volume
28
Category
Article
ISSN
0032-3950

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It has been found that methyl salicylate (MS) undergoes a photoinduced decarboxylation to form phenol with a quantum yield of ca. 8 x The reaction is first order and the rate constant is proportional to the irradiance used. An activation energy of 1.2 kcal/mol was determined. Computer simulations w