Study on kinetics and mechanism of coppe
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Cheng De-Ping; Xia Shi-Jun
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Article
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2010
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John Wiley and Sons
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English
โ 338 KB
๐ 2 views
The copper-catalyzed oxidation of hydrazine by iron(II1) in acid solution follows the rate law -d[Fe(III)]/dt = ~K~[CU(II)]~/(K~ + [H+]), where Kh is the hydrolysis constant of Cu2+, k was found t o be 8.8f0.8, 13.2f1.4 and 17.5f1.3 min-' at 35, 40, and 45OC respectively and p= 0.2 mol/L. The compos